X-ray diffraction (XRD) studies on single-walled carbon nanotube (SWNT) sam
ples prepared by the arc-dischage method were reported. The XRD profile was
basically explained to be a result of triangular packing of SWNTS with a l
attice constant of 17.1 Angstrom and an average nanotube radius of 7.1 Angs
trom. We found an anomalous change in XRD profiles before and after heat-tr
eatment of the SWNT samples in air at similar to 350 degrees C. Combined wi
th gravimetric measurements and resistivity; measurements, a detailed simul
ation of the XRD profiles showed that air (oxygen, and/or nitrogen and/or w
ater) can be condensed inside:the SWNTs.