Study on preparation of chlorinated natural rubber from latex and its thermal stability

Authors
Zhong, JP Li, SD Wei, YC Peng, Z Yu, HP
Citation
Jp. Zhong et al., Study on preparation of chlorinated natural rubber from latex and its thermal stability, J APPL POLY, 73(14), 1999, pp. 2863-2867
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
73
Issue
14
Year of publication
1999
Pages
2863 - 2867
Database
ISI
SICI code
0021-8995(19990929)73:14<2863:SOPOCN>2.0.ZU;2-4
Abstract
The effects of pH value of reaction system, reaction time, and reaction tem perature on the chlorination reaction in the preparation of chlorinated nat ural rubber (CNR) from natural rubber latex were discussed. It has been fou nd from the thermal analysis that the thermal degradation of CNR in nitroge n is a one-step reaction, and 30% carbonide with a stable structure remaine d at 360 to 700 degrees C; whereas the thermo-oxidative degradation of CNR in air is a multistep reaction, and the thermal degradation ratio reaches t o 100% at 560 degrees C. (C) 1999 John Wiley & Sons, Inc.