We demonstrate that semiconducting CdF2 crystals doped with gallium pr
ovide an efficient medium for optical storage of information in static
and dynamic regimes in a temperature range close to 300 K. Ga is a bi
stable center in CdF2 crystals. Illumination by visible and UV light b
elow 500 nm causes phototransformation of these centers from a deep-lo
calized to a shallow-hydrogenic state. They are separated by a vibroni
c barrier that causes metastability below 250 K. The phototransformati
on changes the local polarizability, and thus, the local refractive co
efficient. This, in turn, allows writing a phase hologram with a diffr
action efficiency and decay time being temperature dependent with the
activation energy E-act=0.65+/-0.1 eV. A spontaneous decay of the grat
ing is caused by a thermal recovery of the Ga impurity from the metast
able hydrogenic state to the localized ground state. The writing is a
local process. (C) 1997 American Institute of Physics.