Bis(perfluoroalkyl) nitroxides and perfluoroalkyl nitroalkyl nitroxides generated in SET reactions between perfluorodiacyl peroxides and nitroalkane salts

Authors
Zhao, CX Huang, J Qu, YL Chen, GF Jiang, XK
Citation
Cx. Zhao et al., Bis(perfluoroalkyl) nitroxides and perfluoroalkyl nitroalkyl nitroxides generated in SET reactions between perfluorodiacyl peroxides and nitroalkane salts, J FLUORINE, 98(1), 1999, pp. 61-65
Citations number
25
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
98
Issue
1
Year of publication
1999
Pages
61 - 65
Database
ISI
SICI code
0022-1139(19990810)98:1<61:BNAPNN>2.0.ZU;2-K
Abstract
ESR detection of bis(perfluoroalkyl) nitroxides 11 and perfluoroalkyl nitro alkyl nitroxides 12 in accord with expected products suggests an electron t ransfer mechanism for the reactions between nitroalkane salts 1 and perfluo rodiacyl peroxides 2. Nitroxides 11 and 12 are the spin-adducts of radical intermediates (RRCNO2)-R-1-C-2-N-. (3) and R-f (10) with the nitroso-trap R fNO (9) generated in the reactions. These reactions have served as a useful technique in mechanistic studies of one-electron oxidations of some nitrog en-containing substrates. (C) 1999 Elsevier Science S.A. All rights reserve d.