The Council for Geoscience has been conducting a high-density regional geoc
hemical mapping program since 1973. A total area of 295,000 km(2) (25% of t
he surface area of South Africa) has been covered at a sampling density of
one sample per square kilometer. A helicopter is used to collect first-orde
r stream sediments or representative soil samples. The minus 75 mu m fracti
on of samples is routinely analysed for 24 elements by simultaneous XRF. Th
e results show an excellent correlation between soil chemistry and underlyi
ng geological formations. Background values of elements in soils are determ
ined over different lithological units for the identification of anomalous
values relative to these. The database can be used in exploration, the chem
ical characterisation of different geological units, as well as application
s in environmental and agricultural fields. Results of geochemical mapping
of the Bushveld Complex, South Africa, show a distinct anomaly of platinum
and palladium, apparently related to a stratiform platiniferous reef on the
boundary between the Main and Upper Zones of the Rustenburg Layered Suite.
Geochemical mapping in the vicinity of some areas of mining and ore proces
sing revealed large Cu, Ni, Co and Au anomalies, indicating anthropogenic c
ontamination. Soil geochemistry has also been used, in conjunction with vet
erinary information, to explain livestock illness related to rock and soil
qualities. (C) 1999 Elsevier Science B.V. All rights reserved.