The electronic structure of ultrathin Cu films deposited on top of an FCC-C
o(1 0 0) filmhas been studied by angle- and spin-resolved photoemission. De
position at liquid-nitrogen temperature allows the formation of sharp inter
faces that produces well-defined quantum-well states in the Cu valence band
. Furthermore, short-wavelength quantum-well states originating from the ne
ck of the Cu Fermi surface are only visible after low-temperature depositio
n. Spin-resolved spectra show that these states, which are predicted to dom
inate oscillatory magnetic coupling in multilayers, exhibit minority spin c
haracter. (C) 1999 Elsevier Science B.V. All rights reserved.