Four new triterpenes, eupha-7,24-diene-3 beta,22 beta-diol (1), 20-taraxast
ene-3 alpha,28-diol (2), 3 alpha,27-dihydroxy-28,20 beta-taraxastanolide (3
), and 3 alpha-hydroxy-13(18)-oleanene-27,28-dioic acid (4) have been isola
ted from the heartwood of Melaleuca leucadendron. The structures and stereo
chemistry of 1-4 have been determined by spectroscopic analysis, with compo
unds 3 and 4 being investigated in the forms of their diacetate (3a) and di
methyl (4a) derivative, respectively.