Citation
L. Ruhlmann et al., A polycationic zinc-5,15-dichlorooctaethylporphyrinate- viologen wire, J AM CHEM S, 121(28), 1999, pp. 6664-6667
Citations number
19
Categorie Soggetti
Chemistry & Analysis",Chemistry
Journal title
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN journal
00027863
→ ACNP
Volume
121
Issue
28
Year of publication
1999
Pages
6664 - 6667
Database
ISI
SICI code
0002-7863(19990721)121:28<6664:APZVW>2.0.ZU;2-8
Abstract
Electropolymerization of zinc-10-bipyridinium-octaethyl-porphyrinate by cyc
lic scanning between -0.6 and +1.6 V yields a zigzag configured polymer, wh
ich appears as swollen, vesicular bilayer on atomic force micrographs. The
same procedure leads to micrometer-long wire-shaped linear polymers, if the
5,15-methine bridge carbon atoms are blocked by chlorine substituents. The
wires come in two parallel strands originating from antiparallel face-to-f
ace dimers in the solution.