S. Thirumaran et al., Bond valence sum analysis (BVS) of metal ligand bond lengths in some Zn(II), Cd(II) dithiocarbamate complexes and their adducts, MAIN GR MET, 22(7), 1999, pp. 423-425
Bond valence sums have been calculated for a series of Zn(II), Cd(II) dithi
ocarbamate complexes and their adducts. Values calculated from crystallogra
phic distances predict the correct oxidation state of the metal centre in a
wide range of structural types. The BVS analysis for the bisdithiocarbamat
es of zinc, cadmium and their adducts has confirmed the valency of the cent
ral metal to be 2.0 as expected. In the case of zincdithiocarbamate complex
es, the valence bond sums are in general greater than the sums for the addu
cts. The lower BVS values in the case of adducts are due to the change in c
oordination geometry from tetrahedral to octahedral. But in the case of Cad
mium dithiocarbamate complexes and their adducts no observable changes are
seen in VBS values. Relatively larger size of cadmium ion compared to zinc
ion, alleviates the strain involved in the transformation from tetrahedral
to octahedral geometry.