ALPO-34 and SAPO-34 synthesized by using morpholine as templating agent. FTIR and FT-Raman studies of the host-guest and guest-guest interactions within the zeolitic framework

IR and Raman spectra of morpholine, a structure-directing agent, entrapped within the chabasite-related structures of both ALPO-34 and SAPO-34, are di scussed. It is revealed that some vibrational features of the morpholine, w hich is present in the protonic form, are very sensitive to both host-guest (framework-morpholine) and guest-guest (morpholine-morpholine and morpholi ne-water) interactions occurring within the zeolites. FTIR spectroscopy sho ws that: (a) the NH2 group of the protonated morpholine is H-bonded to the zeolitic frameworks (more strongly in SAPO-34); (b) the CH2 vibrations in t he 1500-1300 cm(-1) region are sensitive to the surrounding being different for the ALPO-34 compared with the SAPO-34. Raman spectroscopy reveals that the ring-breathing mode of the morpholine has a small red-shift (from 822 cm(-1) for the protonated molecule in solution, to 815 cm(-1) in SAPO-34), and is deeply decreased in intensity when the molecule is in the constraine d space of the zeolitic cages. In this case, two new modes at 472 and 245 c m(-1), tentatively assigned to morpholine-framework motions, are also prese nt. IR and Raman bands are better resolved in the case of morpholine in ALP O-34 where the template-framework interactions are weaker. (C) 1999 Elsevie r Science B.V. All rights reserved.