The Almaden district is the largest mercury concentration in the world, wit
h a total content of about 250 000 t of mercury, nearly one third of the kn
own total mercury resources of the Earth. Mercury has been exploited since
the Celtic and Roman times, with peak production during the Renaissance and
between 1939-1945. The district is hosted by a Paleozoic synclinorium over
lying Precambrian rocks. The Paleozoic sequence comprises epicontinental qu
artz arenite rocks, including black shales and quartzites. Diatremes, alkal
ine lavas of different composition, and late tholeiitic diabases account fo
r the Ordovician to Devonian magmatism. The tectonic setting of this comple
x suite corresponds to the intraplate type. The mercury deposits of Almaden
can be classified into two main types: type 1, early stratiform type ores
characterized by cinnabar deposition on the lower Silurian quartzites (Cria
dero quartzite; e.g. the Almaden and El Entredicho deposits), and type 2, l
ate discordant orebodies (e.g. Las Cuevas), largely hosted or related to di
atremes (the 'frailesca rocks') of alkaline basaltic composition. In type 1
cinnabar was deposited during diagenesis, in relation to hydrothermal circ
ulation driven by magmatic activity. Type 2 include a variety of deposits h
aving in common the discordant character of the orebodies (e.g. veins, stoc
kworks, massive replacements), and their wide dispersion along the stratigr
aphic column, i.e. from Lower Silurian (e.g. Nueva Concepcion) to Upper Dev
onian (e.g. Corchuelo).