Thermal and radiation-enhanced diffusion in thin films of the order-disorde
r alloy Cu3Au have been analyzed above and below the transition temperature
. It is demonstrated that thin films grown by molecular beam epitaxy are un
iquely suited for such experiments as the surface provides a dominant and w
ell-characterized sink for migrating defects. The analysis is applied to re
cent experiments. Quantitative predictions of radiation-enhanced diffusion
agree closely with experimental values. Analysis of the tracer-impurity the
rmal diffusion experiments provide host diffusion coefficients in a tempera
ture regime through the transition temperature which were heretofore unavai
lable. [S0163-1829(99) 13725-1].