Absence of simulation evidence for critical depletion in slit pores

Citation
Nb. Wilding et M. Schoen, Absence of simulation evidence for critical depletion in slit pores, PHYS REV E, 60(1), 1999, pp. 1081-1083
Citations number
6
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
60
Issue
1
Year of publication
1999
Pages
1081 - 1083
Database
ISI
SICI code
1063-651X(199907)60:1<1081:AOSEFC>2.0.ZU;2-U
Abstract
Recent Monte Carlo simulation studies of a Lennard-Jones fluid confined to a mesoscopic slit pore have reported evidence of "critical depletion" in th e pore local number density near the liquid-vapor critical point. In this B rief Report we demonstrate that the observed depletion effect is in fact a simulation artifact arising from small systematic errors associated with th e use of long range corrections for the potential truncation. Owing to the large near-critical compressibility, these errors lead to significant chang es in the pore local number density. We suggest ways of avoiding similar pr oblems in future studies of confined fluids. [S1063-651X(99)09007-8].