Comment on "Merging of the alpha and beta relaxations in polybutadiene: A neutron spin echo and dielectric study"

Citation
E. Donth et al., Comment on "Merging of the alpha and beta relaxations in polybutadiene: A neutron spin echo and dielectric study", PHYS REV E, 60(1), 1999, pp. 1099-1102
Citations number
13
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
60
Issue
1
Year of publication
1999
Pages
1099 - 1102
Database
ISI
SICI code
1063-651X(199907)60:1<1099:CO"OTA>2.0.ZU;2-7
Abstract
The evaluation method of dielectric data based on a Williams product ansatz [A. Arbe, D. Richter, J. Colmenero, and B. Farago, Phys. Rev. E 54, 3853 ( 1996)] is not suited to the crossover region of the dynamic glass transitio n. This method is insensitive to the shape, position, or even existence of at least one of the relaxation functions if, in the extrapolation from belo w to above the crossover region, the two processes cross or approach one an other. Since a crossover region without any particular change in the relaxa tion mechanism of these processes can in fact be adjusted by this method, b etter dielectric data for polybutadiene in the gigahertz frequency region a re needed to determine whether or not there are peculiarities in the dielec tric function. It would be an odd assumption that the many particularities in the crossover region in other instances are not reflected in the dielect ric response. [S1063-651X(99)02607-0].