E. Donth et al., Comment on "Merging of the alpha and beta relaxations in polybutadiene: A neutron spin echo and dielectric study", PHYS REV E, 60(1), 1999, pp. 1099-1102
The evaluation method of dielectric data based on a Williams product ansatz
[A. Arbe, D. Richter, J. Colmenero, and B. Farago, Phys. Rev. E 54, 3853 (
1996)] is not suited to the crossover region of the dynamic glass transitio
n. This method is insensitive to the shape, position, or even existence of
at least one of the relaxation functions if, in the extrapolation from belo
w to above the crossover region, the two processes cross or approach one an
other. Since a crossover region without any particular change in the relaxa
tion mechanism of these processes can in fact be adjusted by this method, b
etter dielectric data for polybutadiene in the gigahertz frequency region a
re needed to determine whether or not there are peculiarities in the dielec
tric function. It would be an odd assumption that the many particularities
in the crossover region in other instances are not reflected in the dielect
ric response. [S1063-651X(99)02607-0].