Ti. Serebryakova et al., Influence of addition of calcium hexaboride on the structure and properties of hot-pressed titanium boride ceramic, POWD MET ME, 37(9), 1998, pp. 507-511
In our study of the microstructure of hot-pressed TiB2-x CaB6 specimens we
have found that the amount of CaB6 added affects the grain size. The TiB2 g
rain size decreases when the CaB6 content in the composite exceeds 5%. The
retardation of the grain growth during hot pressing of powder with the comp
osition TiB2-10% CaB6 is attributed to dissolution of Ca in it. A composite
with that composition has a high microhardness and bending strength.