Rhodium amino complexes [Rh(COD)(amine)(2)] PF6 immobilized on poly(4-vinylpyridine) as catalysts in the water gas shift reaction

Authors
Pardey, AJ Fernandez, M Canestrari, M Baricelli, P Lujano, E Longo, C Sartori, R Moya, SA
Citation
Aj. Pardey et al., Rhodium amino complexes [Rh(COD)(amine)(2)] PF6 immobilized on poly(4-vinylpyridine) as catalysts in the water gas shift reaction, REACT KIN C, 67(2), 1999, pp. 325-331
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
67
Issue
2
Year of publication
1999
Pages
325 - 331
Database
ISI
SICI code
0133-1736(199907)67:2<325:RAC[PI>2.0.ZU;2-A
Abstract
Catalysts for the water gas shift reaction prepared from Rh(COD)(amine)(2) PF6 (COD = 1,5-cyclooctadiene, amine 4-picoline, 3-picoline, 2-picoline, py ridine, 3,5-lutidine or 2,6-lutidine) immobilized on poly(4-vinylpyridine) in contact with 80% aqueous 2-ethoxyethanol for 1x10(-4) mol Rh/0.5 g of po lymer, P(CO) = 0.9 atm at 100 degrees C, are described. The role of the coo rdinated amine effect on the catalytic activity was investigated.