Single-electron capacitance spectroscopy precisely measures the energies re
quired to add individual electrons to a quantum dot. The spatial extent of
electronic wave functions is probed by investigating the dependence of thes
e energies on changes in the dot confining potential. For low electron dens
ities, electrons occupy distinct spatial sites localized within the dot. At
higher densities, the electrons become delocalized, and all wave functions
are spread over the full dot area. Near the delocalization transition, the
last remaining localized states exist at the perimeter of the dot, Unexpec
tedly, these electrons appear to bind with electrons in the dot center.