Synthesis of an intermediate for (+/-)-platphyllide through thionyl chloride-pyridine mediated rearrangement

Citation
Ak. Banerjee et al., Synthesis of an intermediate for (+/-)-platphyllide through thionyl chloride-pyridine mediated rearrangement, SYN COMMUN, 29(17), 1999, pp. 2995-3001
Citations number
9
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
17
Year of publication
1999
Pages
2995 - 3001
Database
ISI
SICI code
0039-7911(1999)29:17<2995:SOAIF(>2.0.ZU;2-8
Abstract
The cyclohexadienyl alcohol (3) on treatment with thionyl chloride and pyri dine provided the tetrahydronaphthalene (4) whose transformation to the car bomethoxy tetralone (7), a key intermediate for platphyllide (8), has been accomplished in four steps.