A chiral C-3 triisopropylamine and its silatrane derivatives

Authors
Stachel, SJ Ziller, JW Van Vranken, DL
Citation
Sj. Stachel et al., A chiral C-3 triisopropylamine and its silatrane derivatives, TETRAHEDR L, 40(32), 1999, pp. 5811-5812
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
32
Year of publication
1999
Pages
5811 - 5812
Database
ISI
SICI code
0040-4039(19990806)40:32<5811:ACCTAI>2.0.ZU;2-#
Abstract
The first chiral C-3 triisopropylamine has been prepared with the stereogen ic centers adjacent to the central nitrogen atom. This triol was converted to two new C-3 4,6,11-trimethylsilatranes. An X-ray structure revealed that the methyl substituents adopt sterically congested pseudoaxial orientation s. (C) 1999 Elsevier Science Ltd. All rights reserved.