Separation/preconcentration of lanthanum and europium by micro-column packed with immobilized 1-phenyl-3-methyl-4-bonzoyl-5-pyrazone on microcrystalline naphthalene and determination by electrothermal vaporization inductively coupled plasma-atomic emission spectrometry

A sensitive and rapid method for electrothermal vaporization-inductively co upled plasma atomic emission spectrometry (ETV-ICP-AES) determination of La 3+ and Eu3+ after separation/preconcentration by a micro-column packed with immobilized 1-phenyl-3-methyl-4-bonzoyl-5-pyrazone (PMBP) on microcrystall ine naphthalene has been developed. Various influencing factors, such as th e acidity of the aqueous solution, flow rate, volume of the sample, dimensi on of the microcolumn on the separation and the preconcentration of the ana lyte, have been studied, and the working parameters were optimized experime ntally. The choice of the solvent for dissolving the concentrated material and the effects of diverse ions have also been discussed in detail. The det ection limits for ETV-ICP-AES determinations of La and Eu with PMBP as a ch emical modifier are 160 pg and 30 pg, respectively, under optimized experim ental conditions. Relative standard deviations of 4.2% and 3.1% have been o btained after eight replicate determinations at the 10 ng/ml level for La a nd Eu, respectively. The La and Eu contents in the standard reference mater ial of "Vehicle Exhaust Particulates" (NIES No.8) and "Citrus Leaves" (NIST SRM 1752) determined by the proposed method are in good agreement with the reference values.