Electrospray ionization mass spectrometry in the heterogeneous catalyzed organic reactions: unknown compounds in the pyruvate hydrogenation

Authors
Bartok, M Bartok, T Szollosi, G Felfoldi, K
Citation
M. Bartok et al., Electrospray ionization mass spectrometry in the heterogeneous catalyzed organic reactions: unknown compounds in the pyruvate hydrogenation, CATAL LETT, 61(1-2), 1999, pp. 57-60
Citations number
31
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
CATALYSIS LETTERS
ISSN journal
1011372X → ACNP
Volume
61
Issue
1-2
Year of publication
1999
Pages
57 - 60
Database
ISI
SICI code
1011-372X(1999)61:1-2<57:EIMSIT>2.0.ZU;2-9
Abstract
The transformation of cinchonidine was studied in the presence of hydrogen on Pt/alumina by electrospray ionization mass spectrometry using in-source CID. So far unknown compounds were identified. Further studies on the basis of these new observations may permit to establish a more comprehensive mec hanism of enantioselective hydrogenation of alpha-ketoesters.