A layered silver sulfonate incorporating nine-coordinate Ag-I in a hexagonal grid

Authors
Shimizu, GKH Enright, GD Ratcliffe, CI Preston, KF Reid, JL Ripmeester, JA
Citation
Gkh. Shimizu et al., A layered silver sulfonate incorporating nine-coordinate Ag-I in a hexagonal grid, CHEM COMMUN, (16), 1999, pp. 1485-1486
Citations number
18
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
16
Year of publication
1999
Pages
1485 - 1486
Database
ISI
SICI code
1359-7345(19990821):16<1485:ALSSIN>2.0.ZU;2-4
Abstract
Silver benzenesulfonate is an example of a layered 'inorgano-organic' solid where the inorganic component is comprised of sulfonate-bridged silver(I) centers and the organic moiety is a phenyl group; the resulting network of silver ions forms a planar hexagonal array incorporating a previously unobs erved six-fold metal-bridging mode for the sulfonate ion.