Synthesis of the first complex with acetonine as ligand: the first crystalstructure of an acetonine derivative

Authors
Vicente, J Chicote, MT Guerrero, R de Arellano, MCR
Citation
J. Vicente et al., Synthesis of the first complex with acetonine as ligand: the first crystalstructure of an acetonine derivative, CHEM COMMUN, (16), 1999, pp. 1541-1542
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
16
Year of publication
1999
Pages
1541 - 1542
Database
ISI
SICI code
1359-7345(19990821):16<1541:SOTFCW>2.0.ZU;2-9
Abstract
The complex [Au(acetonine)(2)]ClO4 (3 . ClO4) (acetonine = 2,2,4,4,6-pentam ethyl-2,3,4,5-tetrahydropyrimidine) is obtained by bubbling NH3 through an acetone solution containing equimolar amounts of NaClO4 and [AuCl(tht)] (th t = tetrahydrothiophene); the crystal structure of 3 . ClO4 was determined by X-ray crystallography.