First eta(1)-ligated 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene complexes and the remarkable trihydration reaction of trans-[PtCl2(PMe3)(P3C3Bu3t)]to cis-[PtCl(PMe3)(P3O3C3H5Bu3t)], containing the novel CH(Bu-t)PH(O)C(Bu-t)PH(O)CH(Bu-t)P(O) ring system

Authors
Clendenning, SB Hitchcock, PB Nixon, JF
Citation
Sb. Clendenning et al., First eta(1)-ligated 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene complexes and the remarkable trihydration reaction of trans-[PtCl2(PMe3)(P3C3Bu3t)]to cis-[PtCl(PMe3)(P3O3C3H5Bu3t)], containing the novel CH(Bu-t)PH(O)C(Bu-t)PH(O)CH(Bu-t)P(O) ring system, CHEM COMMUN, (15), 1999, pp. 1377-1378
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
15
Year of publication
1999
Pages
1377 - 1378
Database
ISI
SICI code
1359-7345(1999):15<1377:FE2C>2.0.ZU;2-U
Abstract
The first examples of eta(1)-complexes of 2,4,6-tri-tert-butyl-1,3,5-tripho sphabenzene are described, namely trans-[PtCl2(PR3)(P3C3Bu3t)] (PR3 = PMe3, PEt3, PMe2Ph or PMePh2) and their structures established by P-31 and Pt-19 5 NMR spectroscopy. The unusual molecular structure of cis-[PtCl(PMe3)(P3O3 C3H5Bu3t)], containing the novel CH-(Bu-t)PH(O)C(Bu-t)PH(O)CH(Bu-t)P(O) rin g system, which is formed by the trihydration of trans-[PtCl2(PMe3)(P-3-C3B u3t)] is also reported.