Enantiospecific synthesis of a planar chiral bidentate indenyl-alkoxide complex of zirconium using an axially chiral indene ligand

Authors
Baker, RW Wallace, BJ
Citation
Rw. Baker et Bj. Wallace, Enantiospecific synthesis of a planar chiral bidentate indenyl-alkoxide complex of zirconium using an axially chiral indene ligand, CHEM COMMUN, (15), 1999, pp. 1405-1406
Citations number
18
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
15
Year of publication
1999
Pages
1405 - 1406
Database
ISI
SICI code
1359-7345(1999):15<1405:ESOAPC>2.0.ZU;2-8
Abstract
The reaction of axially chiral (M)-1-(2'-methyl-3'-indenyl)- naphthalene-2- methanol 3 with Zr(NEt2)(4) enantiospecifically provides the planar chiral complex (P)-bis(diethylamido)-[1-(2'-methyl-1'-indenyl)naphthalene-2-methox o]-zirconium 7.