Yz. Wang et al., Preparation and characterization of poly(ethylene oxide)/ montmorillonite intercalation compound, CHEM J CH U, 20(7), 1999, pp. 1143-1147
In this paper , poly(ethylene oxide) /montmorillonite intercalation compoun
d was prepared through solution and melting intercalating, The intercalatio
n compound was characterized by XRD, IR and DSC, etc. PEO molecule couold r
eact with Na+ to form a coordination complex and it was in a spiral conform
ation between montmorillonite layers, so the PEO molecule could not be extr
acted by the solvent. As the molecular thermal action was restricted in the
montmorillonite gallery , the melting peak of the PEO crystal in intercala
tion compound was decreased.