Magnetic-field effects on fractal electrodeposits

Citation
Jmd. Coey et al., Magnetic-field effects on fractal electrodeposits, EUROPH LETT, 47(2), 1999, pp. 267-272
Citations number
17
Categorie Soggetti
Physics
Journal title
EUROPHYSICS LETTERS
ISSN journal
02955075 → ACNP
Volume
47
Issue
2
Year of publication
1999
Pages
267 - 272
Database
ISI
SICI code
0295-5075(199907)47:2<267:MEOFE>2.0.ZU;2-5
Abstract
A uniform magnetic field unexpectedly alters the form of copper deposits gr own in a flat electrochemical cell; the patterns change from radial to unid irectional when the cell is horizontal and vice versa when the cell is vert ical. The electrodeposits are characterised by their chirality and fractal dimension. Complex impedance spectra show that the effective diffusion coef ficient of the copper ions is doubled in a field of 1 T. The results demons trate that the field produces a body force comparable to that of gravity. F rom dimensional analysis, it is inferred that the field modifies convective flow on a scale of a few microns close to the cathode.