L. Mitoseriu et al., A comparative study of the grain size effects on ferro-para phase transition in barium titanate ceramics, FERROELECTR, 223(1-4), 1999, pp. 99-106
Barium titanate ceramics having grain sizes between 0.5 mu m and 20 mu m we
re used in a comparative investigation of the ferro-para phase transition,
by recording the temperature dependencies of the heat capacity and pyrochar
ge. The experimental results and the theoretical approach suggest that inte
rnal stresses are the main cause of the observed grain size effects.