Substitution of side groups is suggested as a method to modify and to
improve the mechanical properties, mainly the brittleness, of polypyrr
ole. In this article poly(3,4-dimethoxypyrrole) (poly(DMOP)), a new su
bstituted polypyrrole, is characterized from a physical point of view.
The thermal, mechanical and electrical conduction behaviour is descri
bed together with some structural findings. This is done by uniaxial c
ontinuous deformation (stress-strain, conductivity-strain), thermoelec
tric and dynamic mechanical measurements.