SYNTHESIS OF NEW DONOR-ACCEPTOR SYSTEMS THROUGH THE ASSOCIATION OF A TETRATHIAFULVALENE CORE AND FULLERENE UNITS

Authors
RAVAINE S DELHAES P LERICHE P SALLE M
Citation
S. Ravaine et al., SYNTHESIS OF NEW DONOR-ACCEPTOR SYSTEMS THROUGH THE ASSOCIATION OF A TETRATHIAFULVALENE CORE AND FULLERENE UNITS, Synthetic metals, 87(1), 1997, pp. 93-95
Citations number
17
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
87
Issue
1
Year of publication
1997
Pages
93 - 95
Database
ISI
SICI code
0379-6779(1997)87:1<93:SONDST>2.0.ZU;2-S
Abstract
The preparation of three molecular assemblies in which a tetrathiafulv alene (TTF) derivative is covalently linked to one, two or four C-60 m olecules is reported. The cyclic voltammograms (CVs) of the supramolec ules are the virtual superposition of those of their donor and accepto r parts. In addition, UV-Vis spectra are highly similar to those of th e TTF precursors, indicating that no spontaneous electronic transfer o ccurs between the fullerene spheres and the TTF core.