Pyridazines, 90. On the synthesis of novel 1,2-diazine containing tricyclic systems: Preparation of tetra-azaphenazines

Citation
G. Heinisch et al., Pyridazines, 90. On the synthesis of novel 1,2-diazine containing tricyclic systems: Preparation of tetra-azaphenazines, HETEROCYCLE, 51(7), 1999, pp. 1625
Citations number
2
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLES
ISSN journal
03855414 → ACNP
Volume
51
Issue
7
Year of publication
1999
Database
ISI
SICI code
0385-5414(19990701)51:7<1625:P9OTSO>2.0.ZU;2-3
Abstract
Reaction of 6-chloro-N-(3,6-dichloropyridazin-4-yl)-3-(4-methoxybenzyl-amin o)-N-propylpyridazine-4-carboxamide (1) under strong basic conditions or wi th a weak base at high temperature was found to result in a ring contractio n to give two isomeric tetraazaphenazines. A tentative mechanism is propose d.