Preparation and properties of biodiesel from Cynara cardunculus L. oil

Citation
Jm. Encinar et al., Preparation and properties of biodiesel from Cynara cardunculus L. oil, IND ENG RES, 38(8), 1999, pp. 2927-2931
Citations number
15
Categorie Soggetti
Chemical Engineering
Journal title
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN journal
08885885 → ACNP
Volume
38
Issue
8
Year of publication
1999
Pages
2927 - 2931
Database
ISI
SICI code
0888-5885(199908)38:8<2927:PAPOBF>2.0.ZU;2-Z
Abstract
A study was made of the reaction of transesterification of Cynara carduncul us L. oil by means of methanol, using sodium hydroxide, potassium hydroxide , and sodium methoxide as catalysts. The objective of the work was to chara cterize the methyl esters for use as biodiesels in internal combustion moto rs. The operation variables used were methanol concentration (5-21 wt %), c atalyst concentration (0.1-1 wt %), and temperature (25-60 degrees C). The evolution of the process was followed by gas chromatography, determining th e concentration of the methyl esters at different reaction times. The biodi esel was characterized by determining its density, viscosity, high heating value, cetane index, cloud and pour points, Ramsbottom carbon residue, char acteristics of distillation, and flash and combustion points according to I SO norms. The biodiesel with the best properties was obtained using 15% met hanol, sodium methoxide as catalyst (1%), and 60 degrees C temperature. Thi s biodiesel has very similar properties to those of diesel no. 2.