We use the optimal fluctuation method to find the density of electron state
s inside the pseudogap in disordered Peierls chains. The electrons are desc
ribed by the one-dimensional Dirac Hamiltonian with randomly varying mass (
the Fluctuating Gap Model). We establish a relation between the disorder av
erage in this model and the quantum-mechanical average for a certain double
-well problem. We show that the optimal disorder fluctuation, which has the
form of a soliton-antisoliton pair, corresponds to the instanton trajector
y in the double-well problem. We use the instanton method developed for the
double-well problem to find the contribution to the density of states from
disorder realizations close to the optimal fluctuation.