N. Fukata et M. Suezawa, Formation energy of self-interstitials in carbon-doped Si determined by optical absorption due to hydrogen bound to self-interstitials, J APPL PHYS, 86(4), 1999, pp. 1848-1853
We determined the formation energy of self-interstitials in carbon (C)-dope
d Si from measurements of optical absorption due to hydrogen (H) bound to i
solated self-interstitials. Specimens of C-doped Si were sealed in quartz c
apsules together with hydrogen (H) gas, with pressure being 1 atm at high t
emperature, and were annealed at high temperature for 1 h followed by quenc
hing in water. We measured their optical absorption spectra at about 7 K wi
th an FT-IR spectrometer. Several peaks coincided with those observed in pr
oton-implanted Si. Hence, we conclude that complexes of simple point defect
s such as vacancies and self-interstitials with hydrogen atoms existed in t
hose specimens. From the quenching temperature dependence of the peaks iden
tified to be H bound to self-interstitials, the formation energy of self-in
terstitials in C-doped Si was estimated to be about 3 eV. (C) 1999 American
Institute of Physics. [S0021-8979(99)08116-5].