Stability constants of thiocyanato complexes of cobalt(II), nickel(II) andcopper(II) in methanol

Authors
Khan, M Bouet, G Tanveer, R Ahmed, R
Citation
M. Khan et al., Stability constants of thiocyanato complexes of cobalt(II), nickel(II) andcopper(II) in methanol, J INORG BIO, 75(2), 1999, pp. 79-83
Citations number
35
Categorie Soggetti
Biochemistry & Biophysics","Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF INORGANIC BIOCHEMISTRY
ISSN journal
01620134 → ACNP
Volume
75
Issue
2
Year of publication
1999
Pages
79 - 83
Database
ISI
SICI code
0162-0134(19990615)75:2<79:SCOTCO>2.0.ZU;2-F
Abstract
A spectrophotometric study of cobalt(II), nickel(II) and copper(II) thiocya nato complexes was carried out in methanol at 25 degrees C and at a constan t ionic strength of 1 M. Under the experimental conditions, two mononuclear complexes are identified with each of the three metal ions. Their stabilit y constants are determined with a recent PC program SIRKO and the calculate d values are: for cobalt, log beta(1) = 1.6, log beta(2) = 2.7; for nickel, log beta(1) = 1.8, log beta(2) = 3.0; and for copper, log beta(1) = 3.0, l og beta(2) = 3.6. (C) 1999 Elsevier Science Inc. All rights reserved.