Photon number squeezing of spectrally filtered optical solitons has be
en observed in the sub-picosecond regime, where the Raman effect chang
es the internal quantum structure of each pulse. 160 fs pulses were pr
opagated down a 10 m optical fibre of anomalous group velocity dispers
ion. At energies below the soliton energy subsequent spectral filterin
g with an optical band-pass squeezed the directly detected photocurren
t fluctuations to 3.2 +/- 0.1 dB (52%) below the shot-noise limit. Thi
s implies 4.5 dB (65%) of soliton photon number squeezing, if detectio
n losses are taken into account. Using a spectral edge filter the spec
tral components of the pulses are shown to contribute asymmetrically t
o the squeezing due to stimulated Raman scattering.