Optimization of the composition for synthesizing the high-T-c phase in Bi(Pb)SrCaCuO system

Authors
Liu, HS Liu, LB Yu, H Zhang, YL Jin, ZP
Citation
Hs. Liu et al., Optimization of the composition for synthesizing the high-T-c phase in Bi(Pb)SrCaCuO system, J MATER SCI, 34(17), 1999, pp. 4329-4332
Citations number
29
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF MATERIALS SCIENCE
ISSN journal
00222461 → ACNP
Volume
34
Issue
17
Year of publication
1999
Pages
4329 - 4332
Database
ISI
SICI code
0022-2461(1999)34:17<4329:OOTCFS>2.0.ZU;2-7
Abstract
The optimal composition for synthesizing the high-T-c phase 2223 in the Pb- doped bismuth oxide system has been presented. It was shown by using DTA, S EM (EDAX) and XRD that a single 2223 phase could be fabricated when the sam ple of a Bi2.1-xPbxSr1.9Ca2.05Cu3.0Oz, where x is between 0.2 and 0.3 (not including the loss of Pb), was sintered at 850-860 degrees C. It was also i ndicated that excessive Pb is more effective than excessive Cu in promoting the formation of 2223. (C) 1999 Kluwer Academic Publishers.