Commercial production of copper by continuous casting in a wheel-and-band m
achine, with suitable modifications to induce high undercooling, is conside
red. Impurities control to a large extent the microstructure and mechanical
properties of the ingot. Suitable solute additives in the molten alloy to
achieve constitutional supercooling during solidification have been analyze
d, with particular emphasis on the presence of lead. Experimental informati
on on the Cu-O-Pb phase diagram has been revised and modeling of the micros
tructure evolution as a function of several casting parameters is being pre
sented. (C) 1999 Kluwer Academic Publishers.