On the pressure and electric field dependencies of the relative permittivity of liquids

Citation
Y. Marcus et G. Hefter, On the pressure and electric field dependencies of the relative permittivity of liquids, J SOL CHEM, 28(5), 1999, pp. 575-592
Citations number
39
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF SOLUTION CHEMISTRY
ISSN journal
00959782 → ACNP
Volume
28
Issue
5
Year of publication
1999
Pages
575 - 592
Database
ISI
SICI code
0095-9782(199905)28:5<575:OTPAEF>2.0.ZU;2-Y
Abstract
The dependencies of the relative permittivity epsilon of over 50 liquids on the pressure P, as (partial derivative ln epsilon/P)(T, P0), and of some 4 0 liquids on the (square of the) electric field E at ambient conditions, as beta = [partial derivative epsilon/partial derivative(E-2)](T, P0) were ob tained from literature data. The function (partial derivative ln epsilon/pa rtial derivative P)(T, P0) was fitted to a simple expression in epsilon and the compressibility, kappa(T). These data were used to obtain the limiting slope for the partial molar volumes and the electrostriction of electrolyt es in various solvents.