New approach to dichloroindium amides

Authors
Prust, J Muller, P Rennekamp, C Roesky, HW Uson, I
Citation
J. Prust et al., New approach to dichloroindium amides, J CHEM S DA, (14), 1999, pp. 2265-2266
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
14
Year of publication
1999
Pages
2265 - 2266
Database
ISI
SICI code
0300-9246(1999):14<2265:NATDA>2.0.ZU;2-Q
Abstract
Two different routes are presented for the synthesis of dichloroindium amid es. On the one hand we prepared (THF)(3)Li(mu-Cl)Cl2InN(SiMe3)(Dipp) (1) (D ipp = 2,6-diisopropylphenyl) by the reaction of indium trichloride with the lithiated aniline, on the other hand Cl2InNEt2 (2) by trimethylsilyl chlor ide elimination. Compound 1 was characterized by X-ray strucural analysis.