Ac. Filippou et al., Triazidogermyl complexes of tungsten: synthesis, crystal structure and hydrolysis to a metallocyclotrigermoxane, J CHEM S DA, (14), 1999, pp. 2267-2268
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
The synthesis and full characterization of the triazidogermyl complexes tra
ns-(eta(5)-C5R5)W(CO)(n)(PMe3)(3-n)Ge(N-3)(3) (2a: R = H, n = 1; 2b: R = Me
, n = 1; 5b: R = Me, n = 2) is reported; the crystal structures of 2a and o
f the metallocyclotrigermoxane [Cp*W(CO)(2)(PMe3)Ge(N-3)(mu(2)-O)](3) . C6H
6 (6b . C6H6), the product of partial hydrolysis of 5b, are described.