Systematic synthesis and photochemistry of tetraaryl porphyrins mono-substituted with a transition metal carbonyl: characterisation of a zinc porphyrin-rhenium carbonyl complex

Authors
Aspley, CJ Smith, JRL Perutz, RN
Citation
Cj. Aspley et al., Systematic synthesis and photochemistry of tetraaryl porphyrins mono-substituted with a transition metal carbonyl: characterisation of a zinc porphyrin-rhenium carbonyl complex, J CHEM S DA, (14), 1999, pp. 2269-2271
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
14
Year of publication
1999
Pages
2269 - 2271
Database
ISI
SICI code
0300-9246(1999):14<2269:SSAPOT>2.0.ZU;2-V
Abstract
A systematic synthesis designed to connect a metalloporphyrin to a metal ca rbonyl moiety is demonstrated through a zinc tetraphenyl porphyrin substitu ted with Re(CO)(3)(4'-methyl-2,2'-bipyridyl)Br via an amide bond; the emiss ion and excited state absorption spectra are dominated by porphyrin transit ions.