Synthesis and characterization of new ruthenium(II) complexes containing diisopropylmethylphosphine

Authors
Bustelo, E Jimenez-Tenorio, M Puerta, MC Valerga, P
Citation
E. Bustelo et al., Synthesis and characterization of new ruthenium(II) complexes containing diisopropylmethylphosphine, J CHEM S DA, (14), 1999, pp. 2399-2404
Citations number
49
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
14
Year of publication
1999
Pages
2399 - 2404
Database
ISI
SICI code
0300-9246(1999):14<2399:SACONR>2.0.ZU;2-9
Abstract
The reaction between RuCl3 and (PPr2Me)-Pr-i in 2-methoxyethanol yielded th e five-co-ordinate complex [RuCl2(CO)((PPr2Me)-Pr-i)(2)] in which the phosp hine groups show a cisoid arrangement. The co-ordination sphere of the ruth enium nucleus can be completed with neutral ligands such as CO, (BuNC)-Bu-t , Hpz, 3,5-dimethylpyrazole and HN=CPh2. Likewise, it reacts with S-donor r eagents like PhSH and 2-sulfanylpyridine and readily undergoes metathesis r eactions with salts of some chelating ligands like NaS2CNEt2, KS2COR (R = M e, Et or Pr-i) and K(acac) which are bonded in a bidentate mode.