Path-integral Monte Carlo simulations for Cs atoms immersed in liquid He-4
are performed to investigate the effects of He-exchange on the D-2-excitati
on energy which shifts or splits depending on the pressure (P) and temperat
ure (T). We find substantial difference in P-dependences of the shift betwe
en the cases with T below and above the lambda-transition temperature, whil
e weak P-dependences are seen for splitting irrespective of T. Microscopic
structures of the liquid around the Cs are investigated through analyses of
the He-exchange and the density inhomogeneity.