Crystallographic parameters of atoms in the single crystals of the compounds RB6 (R=Y, La, Ce, Nd, Sm, Eu, Gd)

Citation
Y. Takahashi et al., Crystallographic parameters of atoms in the single crystals of the compounds RB6 (R=Y, La, Ce, Nd, Sm, Eu, Gd), J PHYS JPN, 68(7), 1999, pp. 2304-2309
Citations number
25
Categorie Soggetti
Physics
Journal title
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
ISSN journal
00319015 → ACNP
Volume
68
Issue
7
Year of publication
1999
Pages
2304 - 2309
Database
ISI
SICI code
0031-9015(199907)68:7<2304:CPOAIT>2.0.ZU;2-X
Abstract
The lattice parameters, bond length between rare-earth metals R and boron a toms, intra- and inter-bond lengths between boron atoms and temperature par ameters of constituent atoms in rare-earth hexaborides RB6 (R=Y, La, Ce, Nd , Sm, Eu, Gd) were determined by analyzing integrated X-ray intensities wit h the use of ultra-short wavelength at room temperature. These parameters w ere related to the peculiar physical properties in the compounds. The Einst ein temperature of rare-earth metals in the crystal structure of RB6 (R=La, Ce, Nd, Sm, Eu, Gd) has also been determined by analyzing the temperature dependence of integrated X-ray intensities. Except for EuBdelta, the value is monotonously decreasing with increasing atomic number.