Crazing in two and three dimensions. 1. Two-dimensional crazing

Citation
Tn. Krupenkin et Gh. Fredrickson, Crazing in two and three dimensions. 1. Two-dimensional crazing, MACROMOLEC, 32(15), 1999, pp. 5029-5035
Citations number
41
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULES
ISSN journal
00249297 → ACNP
Volume
32
Issue
15
Year of publication
1999
Pages
5029 - 5035
Database
ISI
SICI code
0024-9297(19990727)32:15<5029:CITATD>2.0.ZU;2-Z
Abstract
A simple model is proposed to describe crazing in a very thin polymer film. It is argued that if the thickness of the film is below a certain critical value, the craze microstructure becomes similar to the deformation zone (t wo-dimensional neck) with the superimposed fibril structure. Deformation zo ne profile, characteristic fibril size, draw ratio, and critical film thick ness are calculated as functions of material parameters and imposed strain rate. The results obtained are in good agreement with experimental values. The predictions of the model can also be used to verify the model of crazin g in thick films and bulk polymers, which is described in Part 2 of the pre sent series.