H. Kato et al., Influence of solder thickness on interfacial structures and fatigue properties of Cu/Sn/Cu joints, MATER SCI T, 15(7), 1999, pp. 851-856
Copper plates were soldered with tinfoil of different thicknesses to examin
e the influence of the solder thickness on formation of secondary phases at
the interface and fatigue properties. In the case of an initial solder thi
ckness of 60 mu m, the thickness of the eta (Cu6Sn5) phase and the epsilon
(Cu3Sn) phase linearly increased with the square root of the bonding time.
The fatigue strength was 3 MPa and the fatigue life decreased with increasi
ng stress amplitude and hall a low scatter. In the fatigue process, fine cr
acks appeared in the eta phase and propagated in the solder layer. This pro
cess was different from the case of static shear fracture. In the case of a
5 mu m solder thickness, the solder was replaced by secondary phases in a
short time, and only the epsilon phase remained at the interface after a bo
nding time of more than 300 min. The fatigue strength was 13 MPa and was in
dependent of the interfacial structure, but the fatigue life showed a large
scatter. In the fatigue rest, unstable fracture occurred along the interfa
ces, similar to that observed in static shear fracture. From these results,
it was concluded that solder joints become brittle with decreasing solder
thickness.