New 2,5-diazabicyclo[2.2.1]heptanes and their application in the asymmetric addition of diethylzinc to benzaldehyde

Authors
Jordis, U Kesselgruber, M Nerdinger, S Mereiter, K
Citation
U. Jordis et al., New 2,5-diazabicyclo[2.2.1]heptanes and their application in the asymmetric addition of diethylzinc to benzaldehyde, MENDELEEV C, (4), 1999, pp. 147-148
Citations number
12
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436 → ACNP
Issue
4
Year of publication
1999
Pages
147 - 148
Database
ISI
SICI code
0959-9436(199907):4<147:N2ATAI>2.0.ZU;2-V
Abstract
New (1S,4S)-2,5-diazabicyclo[2.2.1]heptane derivatives synthesised by direc ted ortho metalation result in enantioselectivities of up to 78% e.e. when used as catalysts in the addition of diethylzinc to benzaldehyde.