Addition of secondary phosphines to phenylcyanoacetylene as a route to functional phosphines

Citation
Ba. Trofimov et al., Addition of secondary phosphines to phenylcyanoacetylene as a route to functional phosphines, MENDELEEV C, (4), 1999, pp. 163-164
Citations number
12
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436 → ACNP
Issue
4
Year of publication
1999
Pages
163 - 164
Database
ISI
SICI code
0959-9436(199907):4<163:AOSPTP>2.0.ZU;2-4
Abstract
Bis(2-phenylethyl)phosphine 1a and bis(2-phenylpropyl)phosphine 1b react ch emo- and regioselectively with phenylcyano-acetylene to give [bis(2-phenyla lkyl)] (1 -phenyl-2-cyanoethenyl)phosphines 2 and 3 in quantitative total y ields.