Z. Karpati et al., Organic matter in thermal waters of the Pannonian Basin - a preliminary report on aromatic compounds, ORG GEOCHEM, 30(7), 1999, pp. 701-712
About 50 formation waters, produced from wells tapping the aquifers of the
elastic Pannonian Basin and Mesozoic carbonates, were studied by GC-MS for
their content of hexane soluble organic compounds. About half of the waters
studied are hotter than 65 degrees C (the regional threshold of thermal ga
s generation) and always contain a great variety of naturally occurring pol
ycyclic aromatic hydrocarbons (PAH) consisting of aromatic hydrocarbons, he
teroaromatics and in some cases phenols. These waters are not known to be c
onnected with oil pools.
The most characteristic compound classes of six PAM-rich water samples are
discussed here. Mono-, di-, tri- and tetracyclic aromatic and heterocyclic
fused aromatic hydrocarbons are present in these waters but in rather varyi
ng relative proportion. The absence of phenols in two of these waters, one
produced from a carbonate and one from a sandy aquifer, is explained by the
absence of terrestrial kerogen and insufficient maturity (R-0 < 0.45%), re
spectively. (C) 1999 Published by Elsevier Science Ltd. All rights reserved
.